SUMMERS OPTICAL CAT#: 12800
SUMMERS PRODUCT: Primer Base
DATE 06/12/2006

MATERIAL SAFETY DATA SHEET
CATALYST FOR LENS BOND
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Summers Optical assumes no responsibility for personal injury or property damage to vendees, users or third parties caused by the material. Such vendees or users assume all risks associated with the use of the material.

Summers Optical, A Division of EMS Acquisition
1560 Industry Road - P O Box 380 - Hatfield, PA 19440
TEL: (215) 412-8380 - FAX: (215) 412-8450
email: sgkcck@aol.com

24 Hour Emergency Phone # Chemtrec: 800/424-9300

FOR PRODUCT AND SALES INFORMATION
CONTACT SUMMERS OPTICALS OFFICE ABOVE

PRODUCT IDENTIFICATION
COMMERCIAL NAME(S): Urethane Compatible Primer Base Component
TSCA: All ingredients in this product are listed in the TSCA Inventory
HMIS HAZARD RATING:   Health: 2
Reactivity: -0                    
Flammability: 3
PPE – H
PRODUCT CLASS Filled epoxy resin in solvents

COMPOSITION AND INFORMATION ON INGREDIENTS
CHEMICAL IDENTITY:

CAS#

 WT % EXPOSURE LIMITS (PPM)
   

AGGIH
TWA

TLVS
STE L

 OSHA
TWA

PELS
STE L

  
Epoxy terminated urethane
W/ diphenyl methane dii

119796-38-2

 10-30 N/E N/E N/E N/E  
n-Butyl Acetate

1000123-86-4

 10-30

150

 200 150 200     s
Methyl Ethyl Ketone 000078-93-3 10-30  200 300 200 300  s

Crystalline Silica Quartz 

 014808-60-7 10-30 0.1mg/m3  N/E  0.1mg/m3 N/E s

Strontium Chromate

 007789-06-2 10-30  0.05mg/m3  N/E 0.10mg/m3  N/E  s

Cyclohexanone

 000108-94-1 10-30  25 N/E 25 N/E s

n-Butyl Alcohol

 000071-36-3   <5 25 N/E 50 N/E  s

 

HAZARDS IDENTIFICATION

Permissible exposure limits for product:  Not established for product.  See Section II.

ROUTE OF ENTRY AND EFFECTS OF OVEREXPOSURE:

ROUTE OF ENTRY: Inhalation and dermal

INHALATION:

Vapor and mist will irritate nose, throat and respiratory tract. High vapor concentration may cause dizziness, drowsiness and fatigue.

EYE CONTACT:

Vapor, mist or liquid is severely irritating to eyes and cause blurred vision, redness and tearing.

SKIN:

Liquid can cause severe skin irritation with drying, defatting, splitting and cracking on repeated contact.

INGESTION:

Liquid can cause irritation of gastro-intestinal tract followed by nausea and vomiting, abdominal discomfort and rapid pulse.

DELAYED EFFECTS:

Repeated overexposure may cause central nervous systems depression, and kidney/liver damage.

Contains an ingredient listed as known or suspected carcinogen?

NTP: Yes       OSHA: No      IARC: Yes

FIRST AID MEASURES:

EYE CONTACT:

  For eye contact, immediately flush eyes for at least 15 minutes with running water.  Hold eyelids apart to ensure rinsing of the entire eye surface and lids with water.  Get immediate medical attention. 
SKIN CONTACT: Wipe excess material with dry towel.  Then wash exposed areas with plenty of water and soap if available, for several minutes.  Get medical attention if irritation occurs.
INHALATION: If inhaled, remove from area to fresh air.  If not breathing, give artificial respiration.  Get immediate medical attention.  If breathing is difficult, transport to medical facility and if available, give supplemental oxygen.
INGESTION:

If swallowed dilute by giving two (2) glasses of water to drink.  Get immediate medical attention.  Never give anything by mouth to an unconscious person.
GENERAL:

In all cases of doubt, or when symptoms persist, seek medical attention.  Never give anything by mouth to an unconscious person.


FIRE AND EXPLOSION HAZARD DATA

FLASH POINT:

  22°F   -5.56°C

METHOD USED:

 Seta flash
LEL (%): Unknown
UEL (%):

N/Av
FLAMMABILITY CLASSIFICATION:

Flammable

FIRE AND EXPLOSION HAZARDS:

Decomposition and combustion products may be hazardous.  High temperatures may cause pressure build-up in closed containers.  Vapors may accumulate in inadequately ventilated or confided areas.  Vapors may form explosive mixture with air.  Vapors are heavier than air and may travel long distances.  Flashback or flame to the handling site may occur.  Closed containers may explode when exposed to extreme heat.

EXTINGUISHER MEDIA:

 Carbon dioxide, dry chemical, foam.

FIRE FIGHTING PROCEDURES:

 Water spray may be ineffective.  Cool fire exposed containers with water.  Fog nozzles are preferable.  Wear NIOSH/MSHA approved self-contained breathing apparatus and complete protective clothing to prevent contact with skin and eyes.

ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:

Remove all ignition sources.  Wear an air-supplied respirator for an unventilated spill.  Dike and cover spill with non-oxidizable absorbent.  Scoop into containers.  Sprinkle sodium Thiosulfate on the residue and work in.  Scoop into disposal container.  Clean up with water.  Wear appropriate personal protective equipment (see section VIII).

HANDLING AND STORAGE

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:

Keep container tightly closed.  Store in a dry location.  Wear proper personal protective equipment (See section VIII). Wash thoroughly after handling and before smoking or eating.

EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS:

 Good general mechanical ventilation.
RESPIRATORY PROTECTION:

When spraying or applying in any circumstances likely to produce airborne levels of solvent vapors in excess of the TLV, use an organic vapor cartridge or air supplied respirator.
EYE PROTECTION:  Chemical goggles or full-face shield
SKIN PROTECTION: Solvent resistant gloves.
GENERAL: Safety shower, eye wash station and washing facilities should be available.  When using in circumstances where skin contact is likely, use complete protection garments.  

PHYSICAL AND CHEMICAL CHARACTERISTICS
PHYSICAL STATE AND APPEARANCE:

Liquid, yellow

LOW BOILING POINT:

 175°F / 79.44°C
HIGH BOILING POINT: 312°F / 155.54°C
EVAPORATION RATE:

UNKNOWN
VAPOR DENSITY: Heavier than air
% VOLATILES BY VOLUME: 56.3
SPECIFIC GRAVITY: 1.194
LIQUID DENSITY: Heavier than water
WEIGHT PER GALLON: 9.95

VOC (GR/L):

 543
VOC (GR/L, COMBINED): 644

STABILITY AND REACTIVITY DATA

STABILITY:

 Stable

HAZARDOUS POLYMERIZATION:

 Will not occur
INCOMPATABILITY:

Strong oxidizing agents, acids, alkalies, and water

CONDITIONS TO AVOID:

 See incompatibilities above.
HAZARDOUS DECOMPOSITION PRODUCTS:

Oxides of carbon and nitrogen, chromium compounds.


TOXICOLOGICAL INFORMATION

ACUTE ORAL, DERMAL AND INHALATION EFFECTS (LD50 AND LC50)

CAS NUMBER  

LD50

 LC50
119796-38-2  N/AV. N/AV.
000123-86-4  10770 mg/kg, oral, rat  2000 ppm, rat, 4hr
000078-93-3 2740 mg/kg, oral, rat  11700 ppm, rat, 4hr
014808-60-7 5000 mg/kg, oral, rat N/AV.
007789-06-2 3118 mg/kg, oral, rat  N/AV.
000108-94-1 1340 mg/kg, oral, rat 2639 ppm, rat, 4hr

000071-36-3

 1500 mg/kg, oral, rat  8000 ppm, rat, r hr

CARCINOGENICITY:

Chromium Compounds (Strontium Chromate): 

NTP and IARC have determined that there is sufficient evidence for the carcinogenicity of hexavalent chromium compounds both in humans and experimental animals.  Prolonged or repeated inhalation of chromate containing mist or fume may cause ulceration and perforation of nasal septum. Prolonged inhalation may cause liver damage.  Prolonged or repeated eye contact may cause conjunctivitis and skin contact, especially with broken skin, may cause “chrome sores”.
Crystalline Silica (Quartz):

Crystalline silica dust in its neat form is on the IARC monographs on the evaluation of the carcinogenic risk of chemicals to humans (Volume 42, 1987) concludes that there is sufficient evidence for the carcinogenicity of crystalline silica to experimental animals, and there is limited evidence of the carcinogenicity of crystalline silica to humans. IARC Class 2A.

Notice:  There is no data available on the product itself.

ECOLOGICAL INFORMATION

Notice:  There is no data available on the product itself.

DISPOSAL CONSIDERATIONS

WASTE DISPOSAL:

When disposing of this material, ensure that it is packaged, stored, transported and otherwise handled in accordance with local, state and federal regulations.

EPA Waste Numbers:
D-001 (Ignitable)
D-007 (Chromium)

TRANSPORT INFORMATION

DOT (NON-BULK):

PROPER SHIPPING NAME:

PAINT
HAZARD CLASS: 3
UN NUMBER: UN1263
PACKING GROUP: II
LABEL: FLAMMABLE LIQUID

OTHER REGULATORY INFORMATION
TSCA SECTION 8(b) – INVENTORY STATUS: All ingredients in this product are listed in the TSCA Inventory or are exempt from listing.
CANADIAN EPA – DSL INVENTORY STATUS: The DSL status of this product is unknown at this time.
SARA TITLE III SECTION 313 – TOXIC CHEMICAL LIST (TCL):

This product contains a toxic chemical for routine annual “Toxic Chemical Release Reporting” under section 313 (40 CFR 372). This information must be included in all MSDS’s copied or distributed for this product.

000071-36-3   n-Butyl Alcohol
000078-93-3   Methyl Ethyl Ketone
007789-06-2   Strontium Chromate
SARA TITLE II SECTION 302 – CERCLA: 

This product contains no chemical regulated under Section 302 as extremely hazardous chemicals for emergency release notification (CERCLA List).

000071-36-3   n-Butyl Alcohol          5000
000078-93-3   Methyl Ethyl Ketone  5000
000108-94-1   Cyclohexanone          5000
000123-86-4   n-Butyl Acetate         5000
007789-06-2   Strontium Chromate      10

CALIFORNIA PROPISITION 65 REPORTABLE INGREDIENTS:

 

Chemicals known by the state of CA to cause cancer: This product contains the following chemical which is known to the state of California to cause cancer.

007789-060-2 Strontium Chromate
014808-60-7   Crystalline Silica Quartz

Chemicals know by the state of CA to cause reproductive toxicity:  This product does not contain any chemicals currently on the California list of know Reproductive Toxins
TSCA Section 12(b) – Export Notification:

This product contains the following chemicals that required annual or one time export notification per chemical and per country.

000123-86-4   n-Butyl Acetate
CLEAN AIR ACT:

Hazardous Air Pollutants (CAA Section 112):  This product contains the following chemicals regulated under Section 112 for National Emission Standards of Hazardous Air Pollutants notification.

000078-93-3   Methyl Ethyl Ketone
7789-6-2 Strontium Chromate
PENNSYLVANIA RIGHT TO KNOW – REPORTABLE INGREDIENTS:

The following is required composition information.  Also, review Section II for additional information for other chemicals.

000071-36-3   n-Butyl Alcohol
000078-93-3   Methyl Ethyl Ketone
000108-94-1   Cyclohexanone
000123-86-4   n-Butyl Acetate
007780-06-2   Crystalline Silica Quartz
NEW JERSEY RIGHT TO KNOW – REPORTABLE INGREDIENTS:

The following is required composition information.  Also, review Section II for additional information for other chemicals.

000071-36-3   n-Butyl Alcohol
000078-93-3   Methyl Ethyl Ketone
000108-94-1   Cyclohexanone
000123-86-4   n-Butyl Acetate
007780-06-2   Crystalline Silica Quartz

SUMMERS OPTICAL CAT#: 12800
SUMMERS PRODUCT: Accelerator Component
DATE 05/05/2002

MATERIAL SAFETY DATA SHEET
CATALYST FOR LENS BOND
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Summers Optical assumes no responsibility for personal injury or property damage to vendees, users or third parties caused by the material. Such vendees or users assume all risks associated with the use of the material.

Summers Optical, A Division of EMS Acquisition
1560 Industry Road - P O Box 380 - Hatfield, PA 19440
TEL: (215) 412-8380 - FAX: (215) 412-8450
email: sgkcck@aol.com

24 Hour Emergency Phone # Chemtrec: 800/424-9300

FOR PRODUCT AND SALES INFORMATION
CONTACT SUMMERS OPTICALS OFFICE ABOVE

PRODUCT IDENTIFICATION
COMMERCIAL NAME(S):

Activator Accelerator Component
TSCA: All ingredients in this product are listed in the TSCA Inventory
HMIS HAZARD RATING:   Health: 2
Reactivity: -0                    
Flammability: 3
PPE – H
PRODUCT CLASS Modified amines in solvents

COMPOSITION AND INFORMATION ON INGREDIENTS
CHEMICAL IDENTITY:

CAS#

 WT % EXPOSURE LIMITS (PPM)
   

AGGIH
TWA

TLVS
STE L

 OSHA
TWA

PELS
STE L

  

Isopropanol

 000067-63-0 60-90 400  500 400 N/E  

Toluene

 000108-88-3 10-30 50 N/E 100 N/E  s

N-Beta-(Aminoethyl)-Gamma-
Aminopropyltrimethoxysil

 001760-24-3 < 5 N/E N/E N/E N/E  
Phenol 000090-72-2 < 5 5 N/E 10 N/E r

 

HAZARDS IDENTIFICATION

Permissible exposure limits for product:  Not established for product.  See Section II.

ROUTE OF ENTRY AND EFFECTS OF OVEREXPOSURE:

ROUTE OF ENTRY: Inhalation and dermal

INHALATION:

Vapor and mist will irritate nose, throat and respiratory tract. High vapor concentration may cause dizziness, drowsiness and fatigue.

EYE CONTACT:

Vapor, mist or liquid is severely irritating to eyes and cause blurred vision, redness and tearing.

SKIN CONTACT:

Liquid can cause severe skin irritation with drying, defatting, splitting and cracking on repeated contact.

INGESTION:

Liquid can cause irritation of gastro-intestinal tract followed by nausea and vomiting, abdominal discomfort and rapid pulse.

DELAYED EFFECTS:

Repeated overexposure may cause central nervous systems depression, and kidney/liver damage.

Contains an ingredient listed as known or suspected carcinogen?

NTP: No        OSHA: No      IARC: No

FIRST AID MEASURES:

EYE CONTACT:

 For eye contact, immediately flush eyes for at least 15 minutes with running water.  Hold eyelids apart to ensure rinsing of the entire eye surface and lids with water.  Get immediate medical attention.
SKIN CONTACT: Wipe excess material with dry towel.  Then wash exposed areas with plenty of water and soap if available, for several minutes.  Get medical attention if irritation occurs.
INHALATION: If inhaled, remove from area to fresh air.  If not breathing, give artificial respiration.  Get immediate medical attention.  If breathing is difficult, transport to medical facility and if available, give supplemental oxygen.
INGESTION:

If swallowed dilute by giving two (2) glasses of water to drink.  Get immediate medical attention.  Never give anything by mouth to an unconscious person.
GENERAL:

In all cases of doubt, or when symptoms persist, seek medical attention.  Never give anything by mouth to an unconscious person.


FIRE AND EXPLOSION HAZARD DATA

FLASH POINT:

  60°F   15.55°C

METHOD USED:

 Seta flash
LEL (%): N/Av
UEL (%):

N/Av
FLAMMABILITY CLASSIFICATION:

Flammable

FIRE AND EXPLOSION HAZARDS:

Decomposition and combustion products may be hazardous.  High temperatures may cause pressure build-up in closed containers.  Vapors may accumulate in inadequately ventilated or confined areas.  Vapors may form explosive mixture with air.  Vapors are heavier than air and may travel long distances.  Flashback or flame to the handling site may occur.  Closed containers may explode when exposed to extreme heat.

EXTINGUISHER MEDIA:

 Carbon dioxide, dry chemical, foam.

FIRE FIGHTING PROCEDURES:

Water spray may be ineffective.  Cool fire exposed containers with water.  Fog nozzles are preferable.  Wear NIOSH/MSHA approved self-contained breathing apparatus and complete protective clothing to prevent contact with skin and eyes.

ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:

Remove all ignition sources.  Wear an air-supplied respirator for an unventilated spill.  Cover with absorbent.  Scoop into containers using non-sparking tools.  Clean up residue with a suitable cleaning solvent.  Wear appropriate personal protective equipment (see Section VIII).

HANDLING AND STORAGE

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:

Keep container tightly closed.  Isolate from heat, electrical equipment, sparks and flame.  Use grounding and bonding procedures during transfer.  Do not store above 120°F.  Vapors of this product are heavier than air and my collect in low or confined areas.  Empty drums may contain explosive vapors.  Do not cut, puncture or weld on or near drum.  Wear proper personal protective equipment (see Section VIII). Wash thoroughly after handling and before smoking or eating.

EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS:

 Local and/or general ventilation as required to maintain hazardous ingredients below recommended (ACGIH-TLV) or regulated (OSHA-PEL) limits.
RESPIRATORY PROTECTION:

When spraying or applying in any circumstances likely to produce airborne levels of solvent vapors in excess of the TLV, use an organic vapor cartridge or air supplied respirator.
EYE PROTECTION:  Chemical goggles or full-face shield
SKIN PROTECTION: Solvent resistant gloves.
GENERAL: Safety shower, eye wash station and washing facilities should be available.  When using in circumstances where skin contact is likely, use complete protection garments.  

PHYSICAL AND CHEMICAL CHARACTERISTICS
PHYSICAL STATE AND APPEARANCE:

Liquid, clear

LOW BOILING POINT:

 180°F / 82.21°C
HIGH BOILING POINT: 601°F / 316.08°C
EVAPORATION RATE:

Slower than n-butyl acetate
VAPOR DENSITY: Heavier than air
% VOLATILES BY VOLUME: 93.3
SPECIFIC GRAVITY: 0.821
LIQUID DENSITY: lighter than water
WEIGHT PER GALLON: 6.84

VOC (GR/L):

N/Av
VOC (GR/L, COMBINED):

N/Av

STABILITY AND REACTIVITY DATA

STABILITY:

 Stable

HAZARDOUS POLYMERIZATION:

 Will not occur
INCOMPATABILITY:

Strong oxidizing agents, acids, alkalies, and water

CONDITIONS TO AVOID:

 See incompatibilities above.
HAZARDOUS DECOMPOSITION PRODUCTS:

Oxides of carbon and nitrogen, chromium compounds.


TOXICOLOGICAL INFORMATION

ACUTE ORAL, DERMAL AND INHALATION EFFECTS (LD50 AND LC50)

CAS NUMBER  

LD50

 LC50

000067-63-0

 4710 mg/kg, oral, rat 17000 ppm, rat, 4hr
000108-88-3 2600 mg/kg, oral, rat 8800 ppm, rat, 4hr
001760-24-3 7460 mg/kg, oral, rat

N/AV
000090-72-2 1200 mg/kg, oral, rat N/AV
Notice:  There is no data available on the product itself.

ECOLOGICAL INFORMATION

Notice:  There is no data available on the product itself.

DISPOSAL CONSIDERATIONS

WASTE DISPOSAL:

When disposing of this material, ensure that it is packaged, stored, transported and otherwise handled in accordance with local, state and federal regulations.

EPA Waste Numbers:  D-001 (Ignitable)

TRANSPORT INFORMATION

DOT (NON-BULK):

PROPER SHIPPING NAME:

PAINT
HAZARD CLASS: 3
UN NUMBER: UN1263
PACKING GROUP: II
LABEL: FLAMMABLE LIQUID

SPECIAL NOTES

 None

OTHER REGULATORY INFORMATION
TSCA SECTION 8(b) – INVENTORY STATUS:

All ingredients in this product are listed in the TSCA Inventory or are exempt from listing.
CANADIAN EPA – DSL INVENTORY STATUS:

The DSL status of this product is unknown at this time.
SARA TITLE III SECTION 313 – TOXIC CHEMICAL LIST (TCL):

This product contains a toxic chemical for routine annual “Toxic Chemical Release Reporting” under section 313 (40 CFR 372). This information must be included in all MSDS’s copied or distributed for this product.

000067-63-0   Isopropanol
000108-88-3   Toluene
SARA TITLE II SECTION 302 – CERCLA: 

This product contains the following chemicals regulated under Section 302 as extremely hazardous substance(s) for emergency release notification (CERCLA List).

000108-88-3   Toluene

CALIFORNIA PROPISITION 65 REPORTABLE INGREDIENTS:

 

Chemicals known by the state of CA to cause cancer: This product does not contain any chemicals currently on the California list of known carcinogens.

Chemicals know by the state of CA to cause reproductive toxicity:  This product contains the following chemical, which is known to the state of California to cause reproductive toxicity.

000108-88-3   Toluene
TSCA Section 12(b) – Export Notification:

This product contains the following chemicals that required annual or one time export notification per chemical and per country.

000067-63-0   Isopropanol
CLEAN AIR ACT:

Hazardous Air Pollutants (CAA Section 112):  This product contains the following chemicals regulated under Section 112 for National Emission Standards of Hazardous Air Pollutants notification.

000067-56-1 Methyl Alcohol
000108-88-3   Toluene
PENNSYLVANIA RIGHT TO KNOW – REPORTABLE INGREDIENTS:

The following is required composition information.  Also, review Section II for additional information for other chemicals.

000067-56-1   Methyl Alcohol
000067-63-0   Isopropanol
000107-15-3   Ethylenediamine
000108-88-3   Toluene
NEW JERSEY RIGHT TO KNOW – REPORTABLE INGREDIENTS:

The following is required composition information.  Also, review Section II for additional information for other chemicals.

000067-63-0   Isopropanol
000108-88-3   Toluene

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